what is the volume of this kit?

Dear Seller, please inform the manufacturer, that the volume is NOT written on the label or container. I had to go here to find the volume.

is this silicone material extreme soft?

This is not a silicone product it is a polyurethane rubber material. It is a 40 shore A cured hardness. Hope this helps.

What should I use for pigmenting the rubber?

I use SO-Strong black liquid colorant by Smooth On. Just a drop or two goes a long way. Works great.

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Enduro Soft - 2 Part Liquid Polyurethane Casting Rubber - Durable, Rubber Casting Resin - Soft Rubber Feel (2 lb kit (32 oz kit))

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